Melt fracture and rheology of linear low density polyethylene ‐ calcium carbonate composites. Issue 9 (8th December 2016)

• Record Type: Journal Article
• Authors: Barczewski, Mateusz; Lewandowski, Krzysztof; Schmidt, Marcin; Szostak, Marek
• Is Part Of: Polymer engineering & science. Volume 57:Issue 9(2017)
• Page Start: 998
• Page End: 1004
• Publication Date: 2016-12-08
• Subjects: Polymer engineering -- Periodicals; Polymers -- Periodicals; 668.9
• DOI: 10.1002/pen.24477
• Languages: English
• ISSNs: 0032-3888

Abstract

Abstract : Rheological behavior and melt fracture of linear low‐density polyethylene (LLDPE) calcium carbonate (CaCO3 ) composites were investigated. Two types of commercial inorganic fillers were used, unmodified and modified with stearic acid. Rheological capillary studies were conducted to assess the influence of inorganic filler incorporation as well as chemical treatment on the rheological properties and instability sequence of polyethylene‐based composites. Strong suppression of melt flow instabilities was observed for both types of composites. Mooney analysis was applied to examine the influence of mineral filler addition and stearic acid modification on the wall slip. Moreover, chemical treatment of calcium carbonate allows to obtain better dispersion of the inorganic filler in a polymeric matrix. POLYM. ENG. SCI., 57:998–1004, 2017. © 2016 Society of Plastics Engineers