Design, Synthesis, and Characterization of Polyphosphazene Bearing Stable Nitroxide Radicals as Cathode‐Active Materials in Li‐Ion Batteries. Issue 17 (8th June 2017)

• Record Type: Journal Article
• Authors: Yeşilot, Serkan; Hacıvelioğlu, Ferda; Küçükköylü, Sedat; Çelik, Kamile Burcu; Sayan, Gürkan; Demir‐Cakan, Rezan
• Is Part Of: Macromolecular chemistry and physics. Volume 218:Issue 17(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-06-08
• Subjects: cathode materials -- lithium‐ion batteries -- nitroxide radicals -- polyphosphazenes; Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.201700051
• Languages: English
• ISSNs: 1022-1352

Abstract

Abstract : A new and facile synthetic strategy is developed for the synthesis of a polyphosphazene bearing stable nitroxide radicals as a cathode‐active material for rechargeable lithium batteries, which performs over 80 mAh g −1 capacity at a C/2 current density for 50 cycles. Abstract : A new synthetic strategy is developed for the synthesis of polyphosphazene bearing stable nitroxide radicals as a pendant group. The resulting material is investigated as a cathode‐active material for rechargeable lithium–ion batteries that performs 80 mAh g −1 capacities at a C/2 current density over 50 cycles. Thus, the inorganic–organic hybrid system can be proposed as an alternative cathode‐active material with improved performance.