A Boron Alkylidene–Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal. (9th August 2017)
- Record Type:
- Journal Article
- Title:
- A Boron Alkylidene–Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal. (9th August 2017)
- Main Title:
- A Boron Alkylidene–Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal
- Authors:
- Liu, Xun
Deaton, T. Maxwell
Haeffner, Fredrik
Morken, James P. - Abstract:
- Abstract: We describe an unusual net [2+2] cycloaddition reaction between boron alkylidenes and unactivated alkenes. This reaction provides a new method for the construction of carbocyclic ring systems bearing versatile organoboronic esters. Aside from surveying the scope of this reaction, we provide details about the mechanistic underpinnings of this process, and examine its application to the synthesis of the natural product aphanamal.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 38(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 38(2017)
- Issue Display:
- Volume 129, Issue 38 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 38
- Issue Sort Value:
- 2017-0129-0038-0000
- Page Start:
- 11643
- Page End:
- 11647
- Publication Date:
- 2017-08-09
- Subjects:
- Alkene -- Bor -- Cyclisierungen -- Reaktionsmechanismen -- Totalsynthesen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201705720 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 4569.xml