Condensed‐Phase, Halogen‐Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions1. (30th January 2015)
- Record Type:
- Journal Article
- Title:
- Condensed‐Phase, Halogen‐Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions1. (30th January 2015)
- Main Title:
- Condensed‐Phase, Halogen‐Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions1
- Authors:
- Sladojevich, Filippo
McNeill, Eric
Börgel, Jonas
Zheng, Shao‐Liang
Ritter, Tobias - Abstract:
- Abstract: A family of practical, liquid trifluoromethylation and pentafluoroethylation reagents is described. We show how halogen bonding can be used to obtain easily handled liquid reagents from gaseous CF3 I and CF3 CF2 I. The synthetic utility of the new reagents is exemplified by a novel direct arene trifluoromethylation reaction as well as adaptations of other perfluoroalkylation reactions.
- Is Part Of:
- Angewandte Chemie. Volume 127:Number 12(2015)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 127:Number 12(2015)
- Issue Display:
- Volume 127, Issue 12 (2015)
- Year:
- 2015
- Volume:
- 127
- Issue:
- 12
- Issue Sort Value:
- 2015-0127-0012-0000
- Page Start:
- 3783
- Page End:
- 3787
- Publication Date:
- 2015-01-30
- Subjects:
- Arene -- C‐H‐Funktionalisierung -- Halogenbrücken -- Pentafluorethylierungen -- Trifluormethylierungen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201410954 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 4489.xml