Imidazolium cation transportation in a 1-D coordination polymer. Issue 33 (4th August 2017)

• Record Type: Journal Article
• Authors: Chen, Wenqian; Ogiwara, Naoki; Kadota, Kentaro; Panyarat, Kitt; Kitagawa, Susumu; Horike, Satoshi
• Is Part Of: Dalton transactions. Volume 46:Issue 33(2017)
• Page Start: 10798
• Page End: 10801
• Publication Date: 2017-08-04
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt02625k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : We synthesized a coordination polymer, [EtMeIm][Cu(bpy)(Me2 PO4 )3 ], containing an anionic 1-D chain and an ethyl methyl imidazolium cation. Abstract : We synthesized a coordination polymer, [EtMeIm][Cu(bpy)(Me2 PO4 )3 ], containing an anionic 1-D chain and an ethyl methyl imidazolium cation. The organic cations show fast transport behavior, and the observed ion conductivity is 1.4 × 10 −3 S cm −1 at 110 °C. The stability and structure of the material were confirmed by DSC, X-ray adsorption, and long-term AC impedance spectroscopy.