Transition metal-free tandem pyridinyl–allyl–allyl cross-coupling reaction. Issue 18 (17th September 2017)
- Record Type:
- Journal Article
- Title:
- Transition metal-free tandem pyridinyl–allyl–allyl cross-coupling reaction. Issue 18 (17th September 2017)
- Main Title:
- Transition metal-free tandem pyridinyl–allyl–allyl cross-coupling reaction
- Authors:
- Zhang, Lili
Chen, Zhengkai
Li, Hongli
Yin, Wenguang
Xu, Jianfeng
Miao, Maozhong
Ren, Hongjun - Abstract:
- ABSTRACT: A transition metal-free, direct one-pot domino allylation reaction of 2-pyridinyl Grignard reagents with polysubstituted allyl chlorides for the regioselective synthesis of pyridinyl-substituted 1, 5-diene derivatives has been disclosed. The reaction presumably proceeded through the coupling of polysubstituted allyl chloride to 2-PyMgX, which was in situ generated from 2-bromopyridine with i -PrMgCl·LiCl. GRAPHICAL ABSTRACT:
- Is Part Of:
- Synthetic communications. Volume 47:Issue 18(2017)
- Journal:
- Synthetic communications
- Issue:
- Volume 47:Issue 18(2017)
- Issue Display:
- Volume 47, Issue 18 (2017)
- Year:
- 2017
- Volume:
- 47
- Issue:
- 18
- Issue Sort Value:
- 2017-0047-0018-0000
- Page Start:
- 1668
- Page End:
- 1675
- Publication Date:
- 2017-09-17
- Subjects:
- Allylation -- cross-coupling -- metal-free -- pyridines -- tandem reaction
Organic compounds -- Synthesis -- Periodicals
Chemistry, Organic
Synthesis
547.205 - Journal URLs:
- http://www.tandfonline.com/toc/lsyc20/current ↗
http://www.tandfonline.com/ ↗ - DOI:
- 10.1080/00397911.2017.1339803 ↗
- Languages:
- English
- ISSNs:
- 0039-7911
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8586.830000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4467.xml