Ferroelectricity in bis(ethylammonium) pentachlorobismuthate(iii): synthesis, structure, polar and spectroscopic properties. Issue 8 (15th June 2017)

• Record Type: Journal Article
• Authors: Piecha-Bisiorek, Anna; Gągor, Anna; Jakubas, Ryszard; Ciżman, Agnieszka; Janicki, Rafał; Medycki, Wojciech
• Is Part Of: Inorganic chemistry frontiers. Volume 4:Issue 8(2017)
• Page Start: 1281
• Page End: 1286
• Publication Date: 2017-06-15
• Subjects: Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7qi00254h
• Languages: English
• ISSNs: 2052-1553

Abstract

Abstract : A brief description of the thermal, structural and dielectric properties of bis(ethylammonium) pentachlorobismuthate(iii ) ferroelectric with P s that equals to 1.4 μC cm −2 at 180 K is presented. Abstract : A brief description of the thermal, structural and dielectric properties of bis(ethylammonium) pentachlorobismuthate(iii ) ferroelectric with P s that equals to 1.4 μC cm −2 at 180 K is presented. This paper focuses in particular on the molecular mechanism of a phase transition that is related mainly to the deformation of the anionic sublattice confirmed by temperature-variable powdered UV-Vis spectroscopy.