A room-temperature liquid metal-based self-healing anode for lithium-ion batteries with an ultra-long cycle life. Issue 8 (2nd August 2017)

• Record Type: Journal Article
• Authors: Wu, Yingpeng; Huang, Lu; Huang, Xingkang; Guo, Xiaoru; Liu, Dan; Zheng, Dong; Zhang, Xuelin; Ren, Ren; Qu, Deyang; Chen, Junhong
• Is Part Of: Energy & environmental science. Volume 10:Issue 8(2017)
• Page Start: 1854
• Page End: 1861
• Publication Date: 2017-08-02
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/c7ee01798g
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : Benefiting from fluidity and surface tension, materials in a liquid form are one of the best candidates for self-healing applications. Abstract : Benefiting from fluidity and surface tension, materials in a liquid form are one of the best candidates for self-healing applications. This feature is highly desirable for improving the life cycle of lithium-ion batteries (LIBs) because the volume expansion/contraction during the cycles of high-capacity anodes such as Si and Sn can result in mechanical fracture and lead to inferior cycle performance. Here, we report a novel room-temperature liquid metal (LM) as the anode to improve the cycle life of LIBs. The LM anode comprises an alloy of Sn and Ga, a liquid at room temperature with inherent self-healing properties, as confirmed by the in situ and ex situ analyses. Because both Ga and Sn have high theoretical capacities (769 and 990 mA h g −1, respectively), the resulting LM anode delivers a high capacity of 775, 690, and 613 mA h g −1 at the rate of 200, 500, and 1000 mA g −1, respectively. There was no obvious decay in more than 4000 cycles with a capacity of ∼400 mA h g −1 at 4000 mA g −1, realizing the best cycle performance among all metal anodes.