Ionic diffusion and proton transfer in aqueous solutions of alkali metal salts. Issue 31 (24th July 2017)

• Record Type: Journal Article
• Authors: Cassone, Giuseppe; Creazzo, Fabrizio; Giaquinta, Paolo V.; Sponer, Jiri; Saija, Franz
• Is Part Of: Physical chemistry chemical physics. Volume 19:Issue 31(2017)
• Page Start: 20420
• Page End: 20429
• Publication Date: 2017-07-24
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c7cp03663a
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : We report on a series of ab initio molecular dynamics investigations on LiCl, NaCl, and KCl aqueous solutions under the effect of static electric fields. Abstract : We report on a series of ab initio molecular dynamics investigations on LiCl, NaCl, and KCl aqueous solutions under the effect of static electric fields. We have found that although in low-to-moderate field intensity regimes the well-known sequence of cationic mobilities μ (K + ) > μ (Na + ) > μ (Li + ) ( i.e., the bigger the cation the higher the mobility) is recovered, from intense field strengths this intuitive rule is no longer verified. In fact, field-induced water molecular dissociations lead to more complex phenomena regulating the standard migration properties of the simplest monovalent cations. The water dissociation threshold is lowered from 0.35 V Å −1 to 0.25 V Å −1 by the presence of charged species in all samples. However, notwithstanding a one-stage process of water ionization and proton conduction takes place at 0.25 V Å −1 in the electrolyte solutions where "structure maker" cations are present ( i.e., LiCl and NaCl), the KCl aqueous solution shows some hindrance in establishing a proton conductive regime, which is characterized by the same proton conduction threshold of neat water ( i.e., 0.35 V Å −1 ). In addition, it turns out that protons flow easily in the LiCl ( σ p = 3.0 S cm −1 ) solution and then – in descending order – in the NaCl ( σ p = 2.5 S cm −1 ) and KCl ( σ p = 2.3 S cm −1 ) electrolyte solutions. The protonic conduction efficiency is thus inversely proportional to the ionic radii of the cations present in the samples. Moreover, Cl − anions act as a sort of "protonic well" for high field intensities, further lowering the overall proton transfer efficiency of the aqueous solutions. As a consequence, all the recorded protonic conductivities are lower than that for neat water ( σ p = 7.8 S cm −1 ), which strongly indicates that devices exploiting the proton transfer ability should be designed so as to minimize the presence of ionic impurities.