Interconversion of molecular face-rotating polyhedra through turning inside out. Issue 64 (26th June 2017)
- Record Type:
- Journal Article
- Title:
- Interconversion of molecular face-rotating polyhedra through turning inside out. Issue 64 (26th June 2017)
- Main Title:
- Interconversion of molecular face-rotating polyhedra through turning inside out
- Authors:
- Wang, Yu
Fang, Hongxun
Zhang, Wei
Zhuang, Yongbin
Tian, Zhongqun
Cao, Xiaoyu - Abstract:
- Abstract : We report the post-synthesis interconversion of two enantiomeric organic cages through turning inside out. Abstract : We report the post-synthesis interconversion of two enantiomeric organic cages through turning inside out. By scrutinizing the thermodynamics and kinetics, we are able to control the racemization rate by various reaction conditions and reveal that the turning-inside-out interconversion is realized through a partial disassembly pathway. The kinetics investigation also provides insight into the dynamic essence of imine chemistry using different solvents and catalysts.
- Is Part Of:
- Chemical communications. Volume 53:Issue 64(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 64(2017)
- Issue Display:
- Volume 53, Issue 64 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 64
- Issue Sort Value:
- 2017-0053-0064-0000
- Page Start:
- 8956
- Page End:
- 8959
- Publication Date:
- 2017-06-26
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc04159d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4429.xml