Pseudocapacitive performance of manganese oxide coated hierarchical cobalt oxide structure prepared by hydrothermal process. (August 2017)

• Record Type: Journal Article
• Authors: Lin, C.-K.; Lin, P.-C.; Shih, S.-J.; Chang, C.-J.; Shi, J.-B.; Chen, C.-Y.
• Is Part Of: Ceramics international. Volume 43(2017)Supplement 1
• Page Start: S739
• Page End: S746
• Publication Date: 2017-08
• Subjects: A. Powders: chemical preparation -- C. Electrical properties -- E. Capacitors -- E. Electrodes -- Hydrothermal; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2017.05.288
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: In the present study, a manganese (Mn) oxide deposited hierarchical cobalt (Co) oxide structure was prepared as a supercapacitor electrode by a two-step hydrothermal process. A Co-oxide hierarchical structure was first prepared as a template on a graphite substrate by hydrothermal and post heat treatment (calcination) processes. Subsequently, the Mn-oxide was deposited onto the surface of the Co-oxide template to form a Mn-oxide coated hierarchical Co-oxide structure by a secondary hydrothermal process. The effects of calcination time on the material characteristics and pseudocapacitive performance of the Mn-oxide coated structure were investigated. Experimental results showed that the microstructural properties of hydrothermally synthesized Co-oxide with a snowflake-like morphology varied with the calcination conditions. A great improvement of > 100% in capacitance of the Mn-oxide coating was obtained by using a template with a Co-oxide hierarchical structure. Moreover, with high capacitance, the excellent cycling stability of the Mn-oxide coated hierarchical Co-oxide structure exhibited high potential for practical application as a pseudocapacitor.