Cover Picture: Formation of Phenyliodonio‐Substituted Spirofurooxindole Trifluoroacetates from N‐Substituted 3‐Oxopentanediamides via Phenyliodine Bis(trifluoroacetate)‐Mediated Oxidative Cascade Reactions (Adv. Synth. Catal. 15/2017). Issue 15 (7th August 2017)

• Record Type: Journal Article
• Authors: Hu, Bei; Cao, Yang; Zhang, Bobo; Zhang‐Negrerie, Daisy; Du, Yunfei
• Is Part Of: Advanced synthesis & catalysis. Volume 359:Issue 15(2017)
• Page Start: 2522
• Page End: 2522
• Publication Date: 2017-08-07
• Subjects: cascade reactions -- C(sp3)–C(sp2) bond formation -- C(sp2)–O bond formation -- hypervalent iodine(iii) reagents -- iodonio-substituted spirofurooxindole derivatives; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201700920
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract : Theinside cover picture, provided by Yunfei Du and co‐workers, illustrates the reaction of N ‐substituted 3‐oxopentanediamides with phenyliodine bis(trifluoroacetate) (PIFA), which was found to give a novel class of phenyliodonio spirooxindole compounds under metal‐free conditions. The reaction is postulated to undergo a cascade process involving an oxidative C–O bond formation, an oxidative C–C bond formation and a final iodination step. Details can be found in the communication on pages 2542–2548 (B. Hu, Y. Cao, B. Zhang. D. Zhang‐Negrerie, Y. Du, Adv. Synth. Catal 2017, 359, 2542–2548; DOI:10.1002/adsc.201700075 ).