Tuning the fluorescence emission in mononuclear heteroleptic trigonal silver(i) complexes. (20th March 2017)

• Record Type: Journal Article
• Authors: Durini, Sara; Ardizzoia, G. Attilio; Therrien, Bruno; Brenna, Stefano
• Is Part Of: New journal of chemistry. Volume 41:Number 8(2017)
• Page Start: 3006
• Page End: 3014
• Publication Date: 2017-03-20
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c6nj04058f
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Mononuclear heteroleptic trigonal planar silver(i ) complexes have been prepared and characterized, both in solution and in the solid state. Their luminescent behavior was investigated, showing a tunable emission maxima according to the electronic properties of the phosphorous ligand, in the solid state. Abstract : Seven mononuclear heteroleptic silver(i ) complexes, [Ag(N∩N)(PR3 )](NO3 ) (N∩N = 2-(1-(pyridin-2-yl)imidazo[1, 5- a ]pyridin-3-yl)phenol; P = PPh3 (1 ), PMe2 Ph (2 ), PMePh2 (3 ), P( p -tolyl)3 (4 ), P( n Bu)3 (5 ), P(OPh)3 (6 ), and P(OEt)3 (7 )), have been prepared and characterized. In these compounds, N∩N acts as a bidentate ligand with the pyridine ring and the pyridine-like nitrogen of the imidazo[1, 5- a ]pyridine group. The coordination around silver is completed by the monodentate phosphine, the nitrate anion being not bound to the metal, which then displays a trigonal planar geometry as confirmed by the X-ray crystal structure of compounds1, 2, 5 and6 . 31 P{ 1 H} NMR and conductivity measurements were performed to settle on the behavior of these complexes in solution. The photophysical properties of these species have been investigated, both in solution and in the solid state: they showed intense fluorescence when excited with UV light, with λ max of emission comprised between 440–460 nm (in solution) and 460–498 nm (solid state) and lifetime decay of a few nanoseconds. In the solid state, a reasonable tuning of the emission is observed according to the electronic features of the coordinated phosphine.