Concerted Catalysis in Tight Spaces: Palladium‐Catalyzed Allylation Reactions Accelerated by Accumulated Active Sites in Mesoporous Silica. Issue 15 (21st June 2017) - Motokura, Ken
Abstract: The surface of mesoporous silica was modified with a Pd–bisphosphine complex and/or a tertiary amine group for concerted acceleration of allylation reactions. Mesoporous‐silica‐supported catalysts with a 1.6 nm pore diameter showed higher performance than nonporous or larger mesoporous silica‐supported catalysts owing to the accumulation of active sites into a confined space. For the case in which allyl alcohol was used in the reaction, the presence of a silanol group on the surface was quite effective: the turnover number of Pd was nine times greater than that of the homogeneous Pd complex. Abstract : In concert : Concerted catalysis between the Pd complex and tertiary amine/silanol in mesoporous silica enables the highly efficient allylation of nucleophiles with allyl methyl carbonate, allyl acetate, and also allyl alcohol.