Copper‐Decorated Microsized Nanoporous Titanium Dioxide Photocatalysts for Carbon Dioxide Reduction by Water. Issue 15 (26th June 2017)

• Record Type: Journal Article
• Authors: Zhang, Tao; Low, Jingxiang; Huang, Xiaoxi; Al‐Sharab, Jafar F.; Yu, Jiaguo; Asefa, Tewodros
• Is Part Of: ChemCatChem. Volume 9:Issue 15(2017)
• Page Start: 3054
• Page End: 3062
• Publication Date: 2017-06-26
• Subjects: copper -- nanocomposites -- photocatalysis -- reduction -- titanium; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201700512
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: A series of metallic copper (Cu)‐decorated microsized, nanoporous titanium dioxide (TiO2 ) materials with different loadings of Cu were synthesized by in situ hydrolysis of Sn 2+ ‐grafted titanium glycolate microspheres in the presence of Cu 2+ ions. The resulting materials showed good photocatalytic activity for CO2 reduction with water. In particular, the material prepared with an optimal loading of Cu (≈0.4 wt %) exhibited the highest photocatalytic activity for the reduction of CO2 to hydrocarbon fuel (CH4 ), with an efficiency that was 21‐fold higher than that of the most commonly studied and utilized commercial photocatalyst, Degussa P25 TiO2, under similar reaction conditions. Abstract : Active duty : Metallic copper‐decorated nanoporous titanium dioxide (TiO2 ) microparticles that can efficiently photocatalyze the reduction of CO2 with H2 O to a hydrocarbon fuel (CH4 ) are reported. With an optimal loading of Cu, the catalyst shows catalytic activity that is 21‐fold higher than that of commercial TiO2 (P25, Degussa).