Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones. (18th July 2017)
- Record Type:
- Journal Article
- Title:
- Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones. (18th July 2017)
- Main Title:
- Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
- Authors:
- Levashov, Andrey S.
Aksenov, Nicolai A.
Aksenova, Inna V.
Konshin, Valeriy V. - Abstract:
- Abstract : A small library of acetylenic ketones was synthesized by the reaction of tetraalkynyltin reagents with aldehydes. Abstract : The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed.
- Is Part Of:
- New journal of chemistry. Volume 41:Number 16(2017)
- Journal:
- New journal of chemistry
- Issue:
- Volume 41:Number 16(2017)
- Issue Display:
- Volume 41, Issue 16 (2017)
- Year:
- 2017
- Volume:
- 41
- Issue:
- 16
- Issue Sort Value:
- 2017-0041-0016-0000
- Page Start:
- 8297
- Page End:
- 8304
- Publication Date:
- 2017-07-18
- Subjects:
- Chemistry -- Periodicals
Chimie -- Périodiques
540 - Journal URLs:
- http://www.rsc.org/ ↗
http://www.rsc.org/is/journals/current/newjchem/njc.htm ↗ - DOI:
- 10.1039/c7nj01376k ↗
- Languages:
- English
- ISSNs:
- 1144-0546
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6084.319900
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2954.xml