A rapid and convenient method for the preparation of thermochromic VO2 thin films. (October 2017)

• Record Type: Journal Article
• Authors: Tian, Ye; Liu, Dabo; Luo, Fei; Qi, Hongfei
• Is Part Of: Materials research bulletin. Volume 94(2017)
• Page Start: 100
• Page End: 103
• Publication Date: 2017-10
• Subjects: 81.65.Mq -- 81.15.Cd -- 68.55.Nq; A. Optical materials -- D. Optical properties -- D. Phase transitions; Materials -- Periodicals; Crystal growth -- Periodicals; Matériaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Crystal growth; Materials; Periodicals; 620.11
• DOI: 10.1016/j.materresbull.2017.05.050
• Languages: English
• ISSNs: 0025-5408

Abstract

Graphical abstract: Highlights: A simple and efficient route has been developed for the preparation of VO2 thin films. VO2 films annealed at high enough crystallization temperature were obtained and analyzed. Excellent optical modulation both in the visible and near-infrared region has been achieved in the prepared VO2 film. Abstract: The annealing temperature for the preparation of VO2 films with sputtering method have always been applied in the range of 300–500 °C. Herein, a simple and efficient route has been developed for the preparation of VO2 thin films through the thermal oxidation of sputtered vanadium film at 585 °C. Structural, morphological, elemental analysis and thermochromic properties of synthesized VO2 films are reported. Different from the traditional sputtered VO2 films, large change of transmittance has been found in the visible region during phase transition. The present work shows the feasibility to fabricate reliably reproduced high quality VO2 films with reversible phase transition and excellent optical modulation both in the visible and near-infrared region.