3D‐printed jars for ball‐milling experiments monitored in situ by X‐ray powder diffraction. Issue 4 (14th June 2017)

• Record Type: Journal Article
• Authors: Tumanov, Nikolay; Ban, Voraksmy; Poulain, Agnieszka; Filinchuk, Yaroslav
• Is Part Of: Journal of applied crystallography. Volume 50:Issue 4(2017)
• Page Start: 994
• Page End: 999
• Publication Date: 2017-06-14
• Subjects: ball milling -- 3D printing -- in situ powder diffraction; Crystallography -- Periodicals; 548.05
• DOI: 10.1107/S1600576717006744
• Languages: English
• ISSNs: 0021-8898

Abstract

Abstract : Three‐dimensional (3D) printing allows one to design and easily manufacture jars for ball‐milling experiments monitored in situ by X‐ray powder diffraction. These jars have lower background and higher angular resolution than the standard plastic jars used for this purpose. Different designs are available for download in common 3D‐printing formats. Abstract : Mechanochemistry is flourishing in materials science, but a characterization of the related processes is difficult to achieve. Recently, the use of plastic jars in shaker mills has enabled in situ X‐ray powder diffraction studies at high‐energy beamlines. This paper describes an easy way to design and manufacture these jars by three‐dimensional (3D) printing. A modified wall thickness and the use of a thin‐walled sampling groove and a two‐chamber design, where the milling and diffraction take place in two communicating volumes, allow for a reduced background/absorption and higher angular resolution, with the prospect for use at lower‐energy beamlines. 3D‐printed polylactic acid jars show good mechanical strength and they are also more resistant to solvents than jars made of polymethyl methacrylate. The source files for printing the jars are available as supporting information.