A DFT mechanistic study of the organocatalytic asymmetric reaction of aldehydes and homophthalic anhydride. Issue 63 (24th July 2017)
- Record Type:
- Journal Article
- Title:
- A DFT mechanistic study of the organocatalytic asymmetric reaction of aldehydes and homophthalic anhydride. Issue 63 (24th July 2017)
- Main Title:
- A DFT mechanistic study of the organocatalytic asymmetric reaction of aldehydes and homophthalic anhydride
- Authors:
- Trujillo, Cristina
Rozas, Isabel
Botte, Astrid
Connon, Stephen J. - Abstract:
- Abstract : The first study of the cycloaddition of benzaldehyde with homophthalic anhydride under the influence of an alkaloid-based, squaramide substituted bifunctional organocatalyst using DFT methodology is reported. Abstract : The first DFT study of the cycloaddition of benzaldehyde with homophthalic anhydride under the influence of a bifunctional organocatalyst is reported. The catalyst first binds and then deprotonates the anhydride, leading to a squaramide-bound enolate, which then adds to the aldehyde with activation of the electrophile by the catalyst's ammonium ion.
- Is Part Of:
- Chemical communications. Volume 53:Issue 63(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 63(2017)
- Issue Display:
- Volume 53, Issue 63 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 63
- Issue Sort Value:
- 2017-0053-0063-0000
- Page Start:
- 8874
- Page End:
- 8877
- Publication Date:
- 2017-07-24
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc04596d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2937.xml