Reductive amination catalyzed by iridium complexes using carbon monoxide as a reducing agent. Issue 30 (20th July 2017)

• Record Type: Journal Article
• Authors: Moskovets, Alexey P.; Usanov, Dmitry L.; Afanasyev, Oleg I.; Fastovskiy, Vasilii A.; Molotkov, Alexander P.; Muratov, Karim M.; Denisov, Gleb L.; Zlotskii, Semen S.; Smol'yakov, Alexander F.; Loginov, Dmitry A.; Chusov, Denis
• Is Part Of: Organic & biomolecular chemistry. Volume 15:Issue 30(2017)
• Page Start: 6384
• Page End: 6387
• Publication Date: 2017-07-20
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c7ob01005b
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : N -benzyl, dioxalane, halo-, cyclopropanes tolerates. Abstract : Development of novel, sustainable catalytic methodologies to provide access to amines represents a goal of fundamental importance. Herein we describe a systematic study for the construction of a variety of amines catalyzed by a well-defined homogeneous iridium complex using carbon monoxide as a reducing agent. The methodology was shown to be compatible with functional groups prone to reduction by hydrogen or complex hydrides.