Elemental mapping of Mg/Ca intensity ratios in marine mollusc shells using laser-induced breakdown spectroscopy. Issue 8 (26th June 2017)

• Record Type: Journal Article
• Authors: Hausmann, N.; Siozos, P.; Lemonis, A.; Colonese, A. C.; Robson, H. K.; Anglos, D.
• Is Part Of: Journal of analytical atomic spectrometry. Volume 32:Issue 8(2017)
• Page Start: 1467
• Page End: 1472
• Publication Date: 2017-06-26
• Subjects: Atomic spectra -- Periodicals; Atomic absorption spectroscopy -- Periodicals; 543.0858
• DOI: 10.1039/c7ja00131b
• Languages: English
• ISSNs: 0267-9477

Abstract

Abstract : Here we apply Laser Induced Breakdown Spectroscopy (LIBS) to efficiently map the elemental change throughout the growth increments of three mollusc shells. We employ an automated LIBS setup to map the Mg/Ca composition of whole shell sections with over 2000 data points per hour. Abstract : Records of past environmental conditions in shell carbonate are usually derived from compositional analysis ( i.e. trace elements, stable oxygen, carbon, and nitrogen isotopes) performed along the direction of the shell's growth and thus through time. However, compositional variations within isochronous parts of the shell can distort the environmental record and are difficult to assess without extensively mapping the whole shell. Here we apply Laser Induced Breakdown Spectroscopy (LIBS) to efficiently map the elemental change throughout the growth increments of three mollusc shells ( Conomurex fasciatus, Ostrea edulis, Anomalocardia flexuosa ). We employ an automated LIBS setup to map the Mg/Ca composition of whole shell sections with over 2000 data points per hour. By assessing the spatial variability of Mg/Ca intensity ratios this method has the potential to mitigate distorted results while increasing the resolution of derived palaeoenvironmental information.