Evaluation of the heat duty of catalyst-aided amine-based post combustion CO2 capture. (12th October 2017)

• Record Type: Journal Article
• Authors: Srisang, Wayuta; Pouryousefi, Fatemeh; Osei, Priscilla Anima; Decardi-Nelson, Benjamin; Akachuku, Ananda; Tontiwachwuthikul, Paitoon; Idem, Raphael
• Is Part Of: Chemical engineering science. Volume 170(2017)
• Page Start: 48
• Page End: 57
• Publication Date: 2017-10-12
• Subjects: Post combustion CO2 capture -- Catalytic desorption -- Heat duty -- Brønsted acid/Lewis acid site ratio -- Carbamate breakdown -- Solid acid catalyst; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; Chemical engineering; Periodicals; Electronic journals; 660
• DOI: 10.1016/j.ces.2017.01.049
• Languages: English
• ISSNs: 0009-2509

Abstract

Highlights: This is the first full-cycle study on CO2 capture using solid acid catalysts. HZSM-5 and γ-Al2 O3 used in the desorber both successfully decreased the heat duty. HZSM-5 was better than γ-Al2 O3 (cyclic capacity, absorber efficiency and heat duty). Brønsted acid site/Lewis acid site ratio had the most influence on CO2 desorption. Small pore size was detrimental to performance due to mass transfer limitations. Abstract: The role of a solid acid catalyst in reducing the heat duty for solvent regeneration in post-combustion CO2 was elucidated for the first time using two types of solid acid catalysts (HZSM-5 and γ-Al2 O3 ) in the desorber of a bench scale unit for CO2 capture with 5 mol/L MEA solution at the catalyst bed temperature maintained at 85 °C using 15 SLPM of feed gas with composition of 15% CO2 in N2 . The process performance was evaluated in terms of the cyclic capacity, absorption efficiency and heat duty. The results show that HZSM-5 and γ-Al2 O3 facilitated CO2 desorption from a CO2 -loaded MEA solution by increasing both the cyclic capacity and absorption efficiency, thereby lowering the heat duty. HZSM-5 (predominantly a proton donor catalyst) facilitated the carbamate breakdown by providing a free proton, and increased the absorption efficiency by 38% while reducing the heat duty by 42% as compared to the non-catalytic condition. γ-Al2 O3 (predominantly an electron accepter catalyst) improved absorption efficiency by 23.6% and reduced heat duty by 30% over that of the non catalytic conditions. Based on energy distribution analysis, when a catalyst was used, sensible heat decreased while the heat of desorption and heat of vaporization had insignificant changes. A statistical analysis was performed to show which characteristics of the catalysts had the most influence on process performance by testing five catalytic conditions (HZSM-5, γ-Al2 O3, HY, silica-alumina, and no catalyst) with widely different catalytic properties. The resulting correlations indicate that the acid strength of the catalyst had the most important role in facilitating CO2 desorption from a CO2 -loaded MEA solution followed by the Brønsted acid/Lewis acid (B/L) ratio.