Π-Stacking synthon repetitivity in coordination compounds. Issue 25 (24th May 2016)

• Record Type: Journal Article
• Authors: Khavasi, Hamid Reza; Kavand, Sima
• Is Part Of: CrystEngComm. Volume 18:Issue 25(2016)
• Page Start: 4760
• Page End: 4764
• Publication Date: 2016-05-24
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c6ce00838k
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : The π-stacking synthon repetitivity in the crystal structures of HgX2 complexes of N -(1-chloro/bromo-naphthalen-4-yl)pyrazine-2-carboxamide ligands has been investigated. Structural analysis shows these compounds have almost the same propensity for the formation of π–π interactions in supramolecular crystal structures. Abstract : In this report, research on π-stacking synthon repetitivity and the effect of substituents in the crystal structures of HgX2 complexes of N -(1-chloro/bromo-naphthalen-4-yl)pyrazine-2-carboxamide ligands is described. Structural analysis shows that these compounds have almost the same propensity for the formation of π–π interactions in supramolecular crystal structures.