Tuning the basicity of ionic liquids for efficient synthesis of alkylidene carbonates from CO2 at atmospheric pressure. Issue 50 (31st May 2016)
- Record Type:
- Journal Article
- Title:
- Tuning the basicity of ionic liquids for efficient synthesis of alkylidene carbonates from CO2 at atmospheric pressure. Issue 50 (31st May 2016)
- Main Title:
- Tuning the basicity of ionic liquids for efficient synthesis of alkylidene carbonates from CO2 at atmospheric pressure
- Authors:
- Chen, Kaihong
Shi, Guiling
Dao, Rina
Mei, Ke
Zhou, Xiuyuan
Li, Haoran
Wang, Congmin - Abstract:
- Abstract : A method for the efficient synthesis of alkylidene carbonates from CO2 by tuning the basicity of ionic liquids was reported. Abstract : A strategy to achieve the efficient synthesis of alkylidene carbonates from CO2 at atmospheric pressure by tuning the basicity of ionic liquids was developed. Excellent yields were obtained due to basic ionic liquids' dual roles both as absorbents and as activators. The reaction mechanism was investigated through a combination of NMR spectroscopy, controlled experiments and quantum calculations, indicating the importance of a moderate basicity.
- Is Part Of:
- Chemical communications. Volume 52:Issue 50(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 50(2016)
- Issue Display:
- Volume 52, Issue 50 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 50
- Issue Sort Value:
- 2016-0052-0050-0000
- Page Start:
- 7830
- Page End:
- 7833
- Publication Date:
- 2016-05-31
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc02853e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2896.xml