An Azulene‐Fused Tetracene Diimide with a Small HOMO–LUMO Gap. Issue 7 (11th August 2016)
- Record Type:
- Journal Article
- Title:
- An Azulene‐Fused Tetracene Diimide with a Small HOMO–LUMO Gap. Issue 7 (11th August 2016)
- Main Title:
- An Azulene‐Fused Tetracene Diimide with a Small HOMO–LUMO Gap
- Authors:
- Koide, Taro
Takesue, Moritaka
Murafuji, Toshihiro
Satomi, Koichiro
Suzuki, Yasutaka
Kawamata, Jun
Terai, Kengo
Suzuki, Mitsuharu
Yamada, Hiroko
Shiota, Yoshihito
Yoshizawa, Kazunari
Tani, Fumito - Abstract:
- Abstract: A newly prepared tetraazulene‐fused tetracene diimide (TA‐fused TDI) showed absorption in the near‐IR region owing to the effective extension of the π‐conjugated system as well as a large two‐photon absorption cross‐section ( σ (2) =2140 GM) at 950 nm. Four reversible reduction processes and n‐type semiconductivity were also confirmed as attractive electronic properties of this compound. Abstract : Banded together : A tetraazulene‐fused tetracene diimide (see figure), which was prepared by Suzuki–Miyaura cross‐coupling and oxidative cyclization, exhibited near‐IR absorption, strong two‐photon absorption, four reversible reduction processes, and n‐type semiconductivity.
- Is Part Of:
- ChemPlusChem. Volume 82:Issue 7(2017)
- Journal:
- ChemPlusChem
- Issue:
- Volume 82:Issue 7(2017)
- Issue Display:
- Volume 82, Issue 7 (2017)
- Year:
- 2017
- Volume:
- 82
- Issue:
- 7
- Issue Sort Value:
- 2017-0082-0007-0000
- Page Start:
- 1010
- Page End:
- 1014
- Publication Date:
- 2016-08-11
- Subjects:
- absorption -- arenes -- tetracene diimide -- electrochemistry -- fused-ring systems
Chemistry -- Periodicals
540.5 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)2192-6506 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/cplu.201600356 ↗
- Languages:
- English
- ISSNs:
- 2192-6506
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2816.xml