Terminal Oxo and Imido Transition‐Metal Complexes of Groups 9–11. Issue 22 (25th June 2013)

• Record Type: Journal Article
• Authors: Ray, Kallol; Heims, Florian; Pfaff, Florian Felix
• Other Names: Lu Connie C. sponsoringEditor.; Meyer Karsten sponsoringEditor.
• Is Part Of: European journal of inorganic chemistry. Issue 22/23(2013)
• Page Start: 3784
• Page End: 3807
• Publication Date: 2013-06-25
• Subjects: High‐valent compounds -- O li­gands -- N ligands -- Transition metals -- C–H functionalization -- O–O bond formation; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201300223
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: This review summarizes the properties of group 9–11 metal–oxo and metal–imido complexes, which have been either isolated or proposed as reactive intermediates in metal‐catalyzed organic transformations. We begin with a general description of the bonding of transition‐metal–oxo and –imido complexes in various geometries, followed by a discussion of complexes from groups 9–11. The focus of this review is to provide a clear picture of the state of the art as well as insight towards potential future synthetic endeavors. Abstract : This review summarizes the properties of group 9–11 metal–oxo and metal–imido complexes with a focus on providing a clear picture of the state of the art as well as insight towards potential future synthetic endeavors.