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ChemInform Abstract: Synthesis of a New Class of Iminosugars Based on Constrained Azaspirocyclic Scaffolds by Way of Catalytic C—H Amination. Issue 3 (29th December 2015)
Record Type:
Journal Article
Title:
ChemInform Abstract: Synthesis of a New Class of Iminosugars Based on Constrained Azaspirocyclic Scaffolds by Way of Catalytic C—H Amination. Issue 3 (29th December 2015)
Main Title:
ChemInform Abstract: Synthesis of a New Class of Iminosugars Based on Constrained Azaspirocyclic Scaffolds by Way of Catalytic C—H Amination.
Abstract: Iminosugars (VI) and (VII) are synthesized from substrate (I) via Rh‐catalyzed intramolecular amination followed by N‐allylation, metathesis reaction, and either hydrogenation/deprotection or dihydroxylation/deprotection sequences.