Microwave induced "egg yolk" structure in Cr/V-MIL-53. Issue 60 (13th July 2017)

• Record Type: Journal Article
• Authors: Depauw, Hannes; Nevjestić, Irena; De Winne, Jonatan; Wang, Guangbo; Haustraete, Katrien; Leus, Karen; Verberckmoes, An; Detavernier, Christophe; Callens, Freddy; De Canck, Els; Vrielinck, Henk; Van Der Voort, Pascal
• Is Part Of: Chemical communications. Volume 53:Issue 60(2017)
• Page Start: 8478
• Page End: 8481
• Publication Date: 2017-07-13
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc04651k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Using a one pot microwave procedure, mixed-metal "egg yolk" MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. Abstract : Using a one pot microwave procedure, mixed-metal "egg yolk" MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. In contrast, the solvothermal method produces homogeneous mixed-metal MOFs. The influence of Cr and V on the flexibility and breathing was studied via T-XRPD and CO2 adsorption measurements.