Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study. Issue 28 (6th July 2017)

• Record Type: Journal Article
• Authors: Xu, Xiao; Spasojević-de Biré, Anne; Ghermani, Nour Eddine; Wei, Yongge; Novaković, Sladjana; Bošnjaković-Pavlović, Nada; Wu, Pingfan
• Is Part Of: Physical chemistry chemical physics. Volume 19:Issue 28(2017)
• Page Start: 18162
• Page End: 18166
• Publication Date: 2017-07-06
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c7cp01840a
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : A high resolution X-ray diffraction study has been carried out on [(C4 H9 )4 N]2 [V6 O13 {(OCH2 )3 CCH2 OCCH2 CH3 }2 ] (V6–C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. Abstract : A high resolution X-ray diffraction study has been carried out on [(C4 H9 )4 N]2 [V6 O13 {(OCH2 )3 CCH2 OCCH2 CH3 }2 ] (V6–C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.