Facile construction of AuNP modulated SDS-wrapped G-TC-tailored electrode for sensitive detection of ascorbic acid. (16th June 2017)

• Record Type: Journal Article
• Authors: Kashyap, Hemant; Singh, Puneet K.; Verma, Fooleswar; Rai, Vijai K.; Rai, Ankita; Singh, Manorama
• Is Part Of: New journal of chemistry. Volume 41:Number 14(2017)
• Page Start: 6489
• Page End: 6496
• Publication Date: 2017-06-16
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c7nj01032j
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : AuNP modulated SDS wrapped G-TC electrode was fabricated for electrocatalytic oxidation of ascorbic acid with high sensitivity of 4017.0 μA mM −1 . The LOD was calculated to be 0.07 μM and the sensor was investigated for determination of AcA in real sample (Vit. C tablets) with satisfactory results. Abstract : A rapid and sensitive tailor-made electrode based on a gold nanoparticle (AuNP)-modulated hydrophilic sodium dodecylsulfate (SDS)-wrapped graphene (G)-tolonium chloride (TC) (GSTG) nanocomposite was designed step-by-step in an easy and green way for the detection of ascorbic acid (AcA). At a GSTG/chitosan(CHIT)-modified glassy carbon electrode (GCE), the oxidation potential of ascorbic acid not only appeared at a lower overpotential +200 mV vs. Ag/AgCl, but also the anodic current was enhanced about 20.8 times as compared to a bare GCE. Under optimal conditions, a GSTG/CHIT-modified GCE-based electrochemical sensor was fabricated for electrocatalytic oxidation of ascorbic acid with a high sensitivity of 4017.0 μA mM −1 in a wide linear range of 3 × 10 −4 –1 × 10 −2 mM. The limit of detection was calculated to be 0.07 μM and the sensor was also investigated for the determination of ascorbic acid in real samples (Vitamin C tablets) with satisfactory results.