Effect of Donor Strength and Bulk on Thieno[3, 4‐b]‐pyrazine‐Based Panchromatic Dyes in Dye‐Sensitized Solar Cells. Issue 12 (19th May 2017)

• Record Type: Journal Article
• Authors: Liyanage, Nalaka P.; Cheema, Hammad; Baumann, Alexandra R.; Zylstra, Alexa R.; Delcamp, Jared H.
• Is Part Of: ChemSusChem. Volume 10:Issue 12(2017)
• Page Start: 2635
• Page End: 2641
• Publication Date: 2017-05-19
• Subjects: carbon–hydrogen activation -- dye-sensitized solar cells -- near infrared -- proaromaticity -- thienopyrazine; Green chemistry -- Periodicals; Sustainable engineering -- Periodicals; Chemistry -- Periodicals; Chemical engineering -- Periodicals; 660
• DOI: 10.1002/cssc.201700546
• Languages: English
• ISSNs: 1864-5631

Abstract

Abstract: Near‐infrared‐absorbing organic dyes are critically needed in dye‐sensitized solar cells (DSCs). Thieno[3, 4‐b]pyrazine (TPz) based dyes can access the NIR spectral region and show power conversion efficiencies (PCEs) of up to 8.1 % with sunlight being converted at wavelengths up to 800 nm for 17.6 mA cm −2 of photocurrent in a co‐sensitized DSC device. Precisely controlling dye excited‐state energies is critical for good performances in NIR DSCs. Strategies to control TPz dye energetics with stronger donor groups and TPz substituent choice are evaluated here. Additionally, donor size influence versus dye loading on TPz dyes is analyzed with respect to the TiO2 surface protection designed to prevent recombination of electrons in TiO2 with the redox shuttle. Importantly, the dyes evaluated were demonstrated to work well with low Li + concentration electrolytes, with iodine and cobalt redox shuttle systems, and efficiently as part of co‐sensitized devices. Abstract : Dye‐ing to be infrared : Thieno[3, 4‐b]‐pyrazine (TPz)‐based dyes can access the near‐infrared NIR spectral region and show power conversion efficiencies (PCEs) of up to 8.1 % with sunlight being converted at wavelengths up to 800 nm for 17.6 mA cm −2 of photo‐current in a co‐sensitized DSC device. Precise control of dye energetics is demonstrated here.