Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring. Issue 27 (17th March 2017)

• Record Type: Journal Article
• Authors: Hashimoto, Hisako; Komura, Katsuto; Ishizaki, Takatoshi; Odagiri, Yuto; Tobita, Hiromi
• Is Part Of: Dalton transactions. Volume 46:Issue 27(2017)
• Page Start: 8701
• Page End: 8704
• Publication Date: 2017-03-17
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt00505a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Ruthenium and iron complexes featuring a MSi2 H four-centre bonding interaction were synthesized and the interaction was evaluated experimentally and theoretically. Abstract : Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M–Si–H–Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.