A high-spin square planar iron(ii)-siloxide and its tetrahedral allogon – structural and spectroscopic models of Fe-zeolite sites. Issue 57 (5th July 2017)
- Record Type:
- Journal Article
- Title:
- A high-spin square planar iron(ii)-siloxide and its tetrahedral allogon – structural and spectroscopic models of Fe-zeolite sites. Issue 57 (5th July 2017)
- Main Title:
- A high-spin square planar iron(ii)-siloxide and its tetrahedral allogon – structural and spectroscopic models of Fe-zeolite sites
- Authors:
- Pinkert, D.
Keck, M.
Tabrizi, S. Ghassemi
Herwig, C.
Beckmann, F.
Braun-Cula, B.
Kaupp, M.
Limberg, C. - Abstract:
- Abstract : The so far closest molecular model for the α-Fe sites in Fe-zeolites faithfully mimics the unique structure and spectroscopic features. Abstract : The famous α-Fe active sites in Fe-zeolites have recently been revealed to correspond to mononuclear high-spin iron(ii ) centres in square planar coordination environments. Here we report a first iron siloxide complex which represents a faithful structural and spectroscopic model of such sites. Notably, also an allogon with a distorted structure exists and could be crystallised.
- Is Part Of:
- Chemical communications. Volume 53:Issue 57(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 57(2017)
- Issue Display:
- Volume 53, Issue 57 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 57
- Issue Sort Value:
- 2017-0053-0057-0000
- Page Start:
- 8081
- Page End:
- 8084
- Publication Date:
- 2017-07-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc04670g ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2808.xml