Synthesis, structure, and photoluminescent property of a Zn(II) coordination polymer with 3-fold parallel interpenetrated network. Issue 8 (3rd August 2017)

• Record Type: Journal Article
• Authors: Li, Fu-An; Yang, Wei-Chun; Li, Qing-Bin
• Is Part Of: Inorganic and nano-metal chemistry. Volume 47:Issue 8(2017)
• Page Start: 1243
• Page End: 1247
• Publication Date: 2017-08-03
• Subjects: 5-(4-Hydroxypyridinium-1-ylmethyl)isophthalic acid -- 1, 1′-(1, 4-butanediyl)bis(imidazole) -- interpenetrated network -- zinc; Inorganic compounds -- Synthesis -- Periodicals; Nanostructured materials -- Periodicals; Reactivity (Chemistry) -- Periodicals; Inorganic compounds -- Synthesis; Nanostructured materials; Reactivity (Chemistry); Periodicals; 546
• DOI: 10.1080/24701556.2017.1284107
• Languages: English
• ISSNs: 2470-1556

Abstract

ABSTRACT: A novel coordination polymer, [Zn(L)(1, 4-bbi)0.5 ] n (1 ), where H2 L = 5-(4-hydroxypyridinium-1-ylmethyl)isophthalic acid, 1, 4-bbi = 1, 1′-(1, 4-butanediyl)bis(imidazole), has been hydrothermally synthesized and structurally characterized by X-ray diffraction analysis and further characterized by infrared spectra, elemental analysis, and thermogravimetric analysis. Compound1 has a two-dimensional (2D) double-layered structure and exhibits the 3-fold parallel interpenetrated 2D → 3D network motifs, and Zn(II) center has distorted trigonal bipyramidal environment. Meanwhile, the luminescent property of the compound has also been investigated in detail.