Synthesis, crystal structure, luminescent, and gas adsorption properties of a new Zn(II) compound with two different dinuclear [Zn2(COO)3] subunits. Issue 7 (3rd July 2017)

• Record Type: Journal Article
• Authors: Dong, Yanli; Zhou, Pingping
• Is Part Of: Inorganic and nano-metal chemistry. Volume 47:Issue 7(2017)
• Page Start: 1028
• Page End: 1032
• Publication Date: 2017-07-03
• Subjects: Zn(II) compound -- 1, 2, 4, 5-benzenetetracarboxylic acid -- gas adsorption -- luminescence; Inorganic compounds -- Synthesis -- Periodicals; Nanostructured materials -- Periodicals; Reactivity (Chemistry) -- Periodicals; Inorganic compounds -- Synthesis; Nanostructured materials; Reactivity (Chemistry); Periodicals; 546
• DOI: 10.1080/24701556.2016.1241271
• Languages: English
• ISSNs: 2470-1556

Abstract

ABSTRACT: Presented here is a new Zn(II) compound, namely [Zn4 (btec)2 (DMA)3 ]n (1 represents this compound, H4 btec = 1, 2, 4, 5-benzenetetracarboxylic acid, DMA = N, N′-dimethylacetamide). This compound crystallizes in orthorhombic P bca space group with a = 19.053(2) Å, b = 18.8010(6) Å, c = 22.9434(8) Å, α = β = γ = 90°, and Z = 8. Single crystal X-ray diffraction analysis reveals that compound 1 features a three-dimensional (3D) framework based on two different dinuclear [Zn2 (COO)3 ] subunits. In addition, the solid-state luminescent property of 1 and the gas sorption properties of the desolvated 1a were also investigated.