A new 3D rtl-type Cd(II) framework constructed from 1, 3, 5-benzenetricarboxylic acid: Urothermal synthesis, crystal structure, and photoluminescent property. Issue 1 (2nd January 2017)

• Record Type: Journal Article
• Authors: Dong, Yanli; Zhang, Li; Zhang, Yan
• Is Part Of: Inorganic and nano-metal chemistry. Volume 47:Issue 1(2017)
• Page Start: 73
• Page End: 77
• Publication Date: 2017-01-02
• Subjects: Cd(II) compound -- urothermal synthesis -- trinuclear subunit -- luminescence; Inorganic compounds -- Synthesis -- Periodicals; Nanostructured materials -- Periodicals; Reactivity (Chemistry) -- Periodicals; Inorganic compounds -- Synthesis; Nanostructured materials; Reactivity (Chemistry); Periodicals; 546
• DOI: 10.1080/15533174.2016.1149721
• Languages: English
• ISSNs: 2470-1556

Abstract

ABSTRACT: A new Cd(II) compound, namely [Cd3 (BTC)2 (e-urea)4 ]n (1 H3 BTC = 1, 3, 5-benzenetricarboxylic acid, e-urea = ethylene urea), has been synthesized by the urothermal reactions of 1, 3, 5-benzenetricarboxylic acid and Cd(NO3 )2 and further characterized by elemental analysis, powder X-ray diffraction, and single-crystal X-ray diffraction. Compound1 features a three-dimensional (3D) framework based on trinuclear [Cd3 (COO)6 (e-urea)2 ] subunits. By viewing BTC 3−, trinuclear [Cd3 (COO)6 (e-urea)2 ] subunits as 3- and 6-connected nodes, respectively, the whole framework of1 can be simplified into a rtl-type topological network. Moreover, the thermal stability and luminescent property of compound1 were also investigated.