Unifying miscellaneous performance criteria for a prototype supercapacitor via Co(OH)2 active material and current collector interactions. (15th March 2017)

• Record Type: Journal Article
• Authors: WANG, H.X.; ZHANG, W.; DREWETT, N.E.; ZHANG, H.B.; HUANG, K.K.; FENG, S.H.; LI, X.L.; KIM, J.; YOO, S.; DENG, T.; LIU, S.J.; WANG, D.; ZHENG, W.T.
• Is Part Of: Journal of microscopy. Volume 267:Part 1(2017)
• Page Start: 34
• Page End: 48
• Publication Date: 2017-03-15
• Subjects: Cobalt hydroxides -- crystal structures -- current collectors -- redox reactions -- valence bonding; Microscopy -- Periodicals; 502.82
• DOI: 10.1111/jmi.12545
• Languages: English
• ISSNs: 0022-2720

Abstract

Summary: The use of transition metal oxides and hydroxides in supercapacitors can yield high specific capacity electrodes. However, the effect of interaction between active material and current collector has remained unexplored. Here the behaviour of electrodeposited hexagonal cobalt hydroxide nanosheets on a variety of substrates was investigated, and the resulting valence bonding, morphological evolutions and phase transformations examined. It is shown that the electrochemical activity of the face centred cubic (FCC) Ni substrate dramatically decreases cyclability, the FCC Cu substrate also demonstrates decreased performance, and hexagonal carbon nanofibre (CNF) and Ti substrates exhibit far more stability. The miscellaneous roles of valence bonding, redox reactions and crystal structure mismatch between active material and current collector are examined, and their consequences discussed. Using the resulting insights into performance criteria, it was possible to select a suitable substrate for the fabrication of an asymmetric supercapacitor. The high performance and stability of the device demonstrates the usefulness of this approach, and the utility of applying these insights to energy storage devices.