Iridium‐Catalyzed Formyl‐Selective Deuteration of Aldehydes. (7th June 2017)
- Record Type:
- Journal Article
- Title:
- Iridium‐Catalyzed Formyl‐Selective Deuteration of Aldehydes. (7th June 2017)
- Main Title:
- Iridium‐Catalyzed Formyl‐Selective Deuteration of Aldehydes
- Authors:
- Kerr, William J.
Reid, Marc
Tuttle, Tell - Abstract:
- Abstract: We report the first direct catalytic method for formyl‐selective deuterium labeling of aromatic aldehydes under mild conditions, using an iridium‐based catalyst designed to favor formyl over aromatic C−H activation. A good range of aromatic aldehydes is selectively labeled, and a one‐pot labeling/olefination method is also described. Computational studies support kinetic product control over competing aromatic labeling and decarbonylation pathways.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 27(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 27(2017)
- Issue Display:
- Volume 129, Issue 27 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 27
- Issue Sort Value:
- 2017-0129-0027-0000
- Page Start:
- 7916
- Page End:
- 7920
- Publication Date:
- 2017-06-07
- Subjects:
- Aldehyde -- C-H-Aktivierung -- Deuterierung -- Dichtefunktionalrechnungen -- Iridium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201702997 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1372.xml