Visible‐Light Photocatalytic Intramolecular Cyclopropane Ring Expansion. (6th June 2017)
- Record Type:
- Journal Article
- Title:
- Visible‐Light Photocatalytic Intramolecular Cyclopropane Ring Expansion. (6th June 2017)
- Main Title:
- Visible‐Light Photocatalytic Intramolecular Cyclopropane Ring Expansion
- Authors:
- Luis‐Barrera, Javier
Laina‐Martín, Víctor
Rigotti, Thomas
Peccati, Francesca
Solans‐Monfort, Xavier
Sodupe, Mariona
Mas‐Ballesté, Rubén
Liras, Marta
Alemán, José - Abstract:
- Abstract: Described herein is a new visible‐light photocatalytic strategy for the synthesis of enantioenriched dihydrofurans and cyclopentenes by an intramolecular nitro cyclopropane ring expansion reaction. Mechanistic studies and DFT calculations are used to elucidate the key factors in this new ring expansion reaction, and the need for the nitro group on the cyclopropane.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 27(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 27(2017)
- Issue Display:
- Volume 129, Issue 27 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 27
- Issue Sort Value:
- 2017-0129-0027-0000
- Page Start:
- 7934
- Page End:
- 7938
- Publication Date:
- 2017-06-06
- Subjects:
- Dichtefunktionalrechnungen -- Kleinringsysteme -- Photokatalyse -- Reaktionsmechanismen -- Ringerweiterung
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201703334 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1372.xml