Two new organic-inorganic hybrid compounds induced by γ-[Mo8O26]4− and [PMo12O40]3−. Issue 11 (3rd June 2017)

• Record Type: Journal Article
• Authors: Ying, Jun; Li, Ting-Ting; Liu, Jia-Ni; Tian, Yan; Ni, Huai-Ping; Ji, Xue-Bin; Liu, Guo-Cheng; Tian, Ai-Xiang
• Is Part Of: Journal of coordination chemistry. Volume 70:Issue 11(2017)
• Page Start: 1872
• Page End: 1881
• Publication Date: 2017-06-03
• Subjects: Polyoxomolybdates -- flexible organic ligand -- electrochemical property -- photocatalysis; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2017.1320395
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: Two new organic–inorganic hybrid compounds, [Cu II (btb)1.5 ( γ -Mo8 O26 )0.5 (H2 O)]·2H2 O (1 ) and [Cu II 2 (btb)4 (PMo V Mo VI 11 O40 )]·2H2 O (2 ) (btb = 4-butyl-1, 4-bis(1, 2, 4-triazole), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, IR spectra and elemental analyses. In1, there exists a ladder-like metal-organic chain with the bidentate [ γ -Mo8 O26 ] 4− anions inserting into the grids. Adjacent chains share the same Cu-btb lines of the ladder to form a 2-D layer. Compound2 also has a ladder-like metal-organic chain. The tetradentate [PMo12 O40 ] 3− anions embed in the grids. The same Cu-btb line is shared by adjacent chains to build a 2-D layer. The btb ligands link adjacent layers to form a 3-D framework. Moreover, we also have investigated the electrochemical and photocatalytic properties of1 and2 . Abstract :