Tandem Michael addition–Claisen-type condensation of anions of O-ethyl carbonates of cyanohydrins to cyclohex-2-en-1-one. Issue 13 (3rd July 2017)
- Record Type:
- Journal Article
- Title:
- Tandem Michael addition–Claisen-type condensation of anions of O-ethyl carbonates of cyanohydrins to cyclohex-2-en-1-one. Issue 13 (3rd July 2017)
- Main Title:
- Tandem Michael addition–Claisen-type condensation of anions of O-ethyl carbonates of cyanohydrins to cyclohex-2-en-1-one
- Authors:
- Torres Domínguez, Héctor M.
Maldonado, Luis A.
Le Lagadec, Ronan - Abstract:
- ABSTRACT: A one pot method for the synthesis of ethyl 2-acetoxy-6-aroylcyclohex-1-ene-1-carboxylates and ethyl 2-acetoxy-6-heterocarbonylcyclohex-1-ene-1-carboxylates through Michael addition of the anions of ethyl carbonates of cyanohydrins to cyclohex-2-en-1-one and subsequent reaction with acetic anhydride is described. These compounds are potential intermediates for the synthesis of 9, 10-anthraquinone and heterofused 1, 4-naphthoquinone derivatives. GRAPHICAL ABSTRACT:
- Is Part Of:
- Synthetic communications. Volume 47:Issue 13(2017)
- Journal:
- Synthetic communications
- Issue:
- Volume 47:Issue 13(2017)
- Issue Display:
- Volume 47, Issue 13 (2017)
- Year:
- 2017
- Volume:
- 47
- Issue:
- 13
- Issue Sort Value:
- 2017-0047-0013-0000
- Page Start:
- 1250
- Page End:
- 1255
- Publication Date:
- 2017-07-03
- Subjects:
- Cyanohydrins -- cyclohexene carboxylates -- tandem Michael addition–Claisen condensation
Organic compounds -- Synthesis -- Periodicals
Chemistry, Organic
Synthesis
547.205 - Journal URLs:
- http://www.tandfonline.com/toc/lsyc20/current ↗
http://www.tandfonline.com/ ↗ - DOI:
- 10.1080/00397911.2017.1322106 ↗
- Languages:
- English
- ISSNs:
- 0039-7911
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8586.830000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1555.xml