Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru–Mn(iii) 1D cyanide-bridged complexes. Issue 22 (24th May 2017)

• Record Type: Journal Article
• Authors: Zhu, Xiaoquan; Su, Shaodong; Cao, Wenhai; Wen, Yuehong; Hu, Shengmin; Wu, Xintao; Sheng, Tianlu
• Is Part Of: Dalton transactions. Volume 46:Issue 22(2017)
• Page Start: 7267
• Page End: 7272
• Publication Date: 2017-05-24
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt01218g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Redox active Ru-based cyanide bridges Mn(iii ) fragments with different oxidation states and forms two new 1D compounds, of which one shows simple paramagnetism and another shows slow magnetic relaxation. Abstract : A new one-dimensional cyanide-bridged complex [Mn III (salphen)Ru II (DMAP)4 (CN)2 ](PF6 ) (1 ) and its oxidized derivative [Mn III (salphen)Ru III (DMAP)4 (CN)2 ](PF6 )2 (2 ) have been synthesized and fully characterized. Magnetic measurements showed that1 shows simple paramagnetism but2 shows intrachain ferromagnetic interaction with slow magnetic relaxation.