Amorphous–amorphous transition in a porous coordination polymer. Issue 52 (16th June 2017)
- Record Type:
- Journal Article
- Title:
- Amorphous–amorphous transition in a porous coordination polymer. Issue 52 (16th June 2017)
- Main Title:
- Amorphous–amorphous transition in a porous coordination polymer
- Authors:
- Ohtsu, Hiroyoshi
Bennett, Thomas D.
Kojima, Tatsuhiro
Keen, David A.
Niwa, Yasuhiro
Kawano, Masaki - Abstract:
- Abstract : The amorphous state plays a key role in porous coordination polymer and metal–organic framework phase transitions. Abstract : The amorphous state plays a key role in porous coordination polymer and metal–organic framework phase transitions. We investigate a crystalline-to-amorphous-to-amorphous-to-crystalline (CAAC) phase transition in a Zn based coordination polymer, by X-ray absorption fine structure (XAFS) and X-ray pair distribution function (PDF) analysis. We show that the system shows two distinct amorphous phases upon heating. The first involves a reversible transition to a desolvated form of the original network, followed by an irreversible transition to an intermediate phase which has elongated Zn–I bonds.
- Is Part Of:
- Chemical communications. Volume 53:Issue 52(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 52(2017)
- Issue Display:
- Volume 53, Issue 52 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 52
- Issue Sort Value:
- 2017-0053-0052-0000
- Page Start:
- 7060
- Page End:
- 7063
- Publication Date:
- 2017-06-16
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc03333h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2220.xml