Copper‐Catalyzed Vinylsilane Allylation. Issue 1 (19th November 2013)

• Record Type: Journal Article
• Authors: Cornelissen, Loïc; Vercruysse, Sébastien; Sanhadji, Ayoub; Riant, Olivier
• Is Part Of: European journal of organic chemistry. Issue 1(2014)
• Page Start: 35
• Page End: 38
• Publication Date: 2013-11-19
• Subjects: Copper -- Silicon -- Vinylsilanes -- Allylation -- Cross‐coupling; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201301360
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: Soft reaction conditions, particularly important in total synthesis, have dragged many researchers into the field of silylated organic compounds. Hereby, we describe a new copper‐catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using a copper(I) salt, and this led to the formation of polysubstituted 1, 4‐dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. Abstract : Hereby is described a new copper‐catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using copper(I) salts, and this led to the formation of polysubstituted 1, 4‐dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. TBAT = tetrabutylammonium difluorotriphenylsilicate.