Synergistic Recognition of Halide Anions and Saccharides by Oligohydrazide Foldamers. Issue 36 (21st October 2013)

• Record Type: Journal Article
• Authors: Bie, Fusheng; Wang, Ying; Shang, Jie; Gallagher, Nolan M.; Jiang, Hua
• Is Part Of: European journal of organic chemistry. Issue 36(2013)
• Page Start: 8135
• Page End: 8144
• Publication Date: 2013-10-21
• Subjects: Host‐guest systems -- Anions -- Carbohydrates -- Macrocycles -- Crown compounds; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201300817
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: We synthesized and characterized a new kind of hydrazide oligomer that contains two different types of binding moieties for halide anions and saccharides. The addition of either halide anions or saccharides can induce the oligomers to adopt folded conformations. More interestingly, the oligomers are able to complex both chloride anions and saccharides in the cavity at the same time, implying a synergistic molecular recognition. Abstract : Benzoylbenzohydrazide oligomers containing two different types of binding moieties could be induced to adopt folded conformations by halide anions and saccharides. Moreover, the oligomers could synergistically host these two different kinds of guests in the cavity.