Interface structure, precursor rheology and dielectric properties of BaTiO3/PVDF–hfp nanocomposite films prepared from colloidal perovskite nanoparticles. Issue 52 (27th June 2017)

• Record Type: Journal Article
• Authors: Hao, Y. N.; Bi, K.; O'Brien, S.; Wang, X. X.; Lombardi, J.; Pearsall, F.; Li, W. L.; Lei, M.; Wu, Y.; Li, L. T.
• Is Part Of: RSC advances. Volume 7:Issue 52(2017)
• Page Start: 32886
• Page End: 32892
• Publication Date: 2017-06-27
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c7ra03250a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A novel and greatly simplified strategy was developed to fabricate high-permittivity dielectric nanocomposites. Interface structure, precursor rheology and dielectric properties of the 0–3 BaTiO3 /PVDF–hfp nanocomposite film were investigated. Abstract : Nanocomposite materials with uniform microstructure and high permittivity have attracted extensive interest in modern electronics. The compatibility between the filler phase and the polymer matrix is crucial in preparing high-performance composites. As an alternative to conventional surface modification treatment methodologies, hydroxylated colloidal BaTiO3 (BT) nanoparticles synthesized via a green and scalable process were directly used to fabricate high-permittivity nanocomposites. Interfacial interaction analyses between the BT nanoparticles and polymer matrix reveals that due to strong hydrogen bonding at the interface, transparent composite sols with excellent flow behavior can be observed. The sols are ideal formulations for the preparation of BT/PVDF–hfp 0–3 nanocomposite films. Owing to the unique interface structure, the composite films show a dense and uniform microstructure and superior dielectric properties. Parallel plate capacitor devices and the co-development of a sandwich architecture leads to the ability to prepare dielectric films with favorable performance characteristics. This method provides a novel and greatly simplified strategy for the fabrication of high-permittivity dielectric nanocomposites.