Detailed Geometric and Electronic Structures of a One‐Electron‐Oxidized Ni Salophen Complex and Its Amido Derivatives. Issue 22 (August 2014)

• Record Type: Journal Article
• Authors: Lecarme, Laureline; Chiang, Linus; Philouze, Christian; Jarjayes, Olivier; Storr, Tim; Thomas, Fabrice
• Is Part Of: European journal of inorganic chemistry. Issue 22(2014)
• Page Start: 3442
• Page End: 3442
• Publication Date: 2014-08
• Subjects: Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201402643
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: Invited for the cover of this issue is the group of Fabrice Thomas at Université Grenoble Alpes, France, collaborating with the group of Tim Storr at Simon Fraser University, Canada. The cover image shows the correlation between the low‐energy near‐infrared absorption spectrum and the spin density in three radical complexes, illustrating the delocalization of the spin density in salen radical complexes. Mountains that surround the cities of Grenoble and Vancouver fit nicely into the background. Abstract : The biggest surprise in this work was the non‐innocence of the aromatic bridge in mediating the electronic communication between the phenolate and phenoxyl rings... Read more about the story behind the cover in the Cover Profile and about the research itself onp. 3479 ff .