Potential of polymethacrylate pseudo crown ethers as solid state polymer electrolytes. Issue 51 (13th June 2017)

• Record Type: Journal Article
• Authors: Moins, S.; Martins, J. C.; Krumpmann, A.; Lemaur, V.; Cornil, J.; Delbosc, N.; Decroly, A.; Dubois, Ph.; Lazzaroni, R.; Gohy, J.-F.; Coulembier, O.
• Is Part Of: Chemical communications. Volume 53:Issue 51(2017)
• Page Start: 6899
• Page End: 6902
• Publication Date: 2017-06-13
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc02385e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The association of kinetic studies, DFT calculations and 1 H– 7 Li NMR analyses allowed the control of the cyclo -ATRP of PEG9 DMA and the production of polymethacrylate pseudo crown-ethers of various molar masses. Abstract : The association of kinetic studies, DFT calculations and 1 H– 7 Li NMR analyses allowed the control of the cyclo -ATRP of PEG9 DMA and the production of polymethacrylate pseudo crown-ethers of various molar masses. Their potential to act as a solid-state polymer electrolyte in Li-ion batteries has been highlighted and may come from the supramolecular organization of the cyclo -PEG forming a Li + diffusion channel.