A new methyl-embedded (3, 36)-connected txt-type metal–organic framework exhibiting high H2 adsorption property. Issue 23 (24th May 2017)

• Record Type: Journal Article
• Authors: Du, Liting; Zhang, Jinchi; Lu, Zhiyong; Duan, Jingui; Xu, Li
• Is Part Of: CrystEngComm. Volume 19:Issue 23(2017)
• Page Start: 3094
• Page End: 3097
• Publication Date: 2017-05-24
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c7ce00461c
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A new methyl-embedded (3, 36)-connected txt -type metal–organic framework was successfully synthesized and it exhibits high H2 uptake capacity. Abstract : A new methyl-embedded (3, 36)-connected txt -type metal–organic framework, {Cu2 (DCPEMP)·H2 O} n (NJFU-4, H4 DCPEMP = 3, 5-bis(3, 5-dicarboxylphenylethynyl)-4-methylpyridine), was solvothermally synthesized and structurally characterized, which exhibits a BET surface area of 2160 m 2 g −1, high stability and high H2 uptake capacity (2.61 wt% at 1 bar and 77 K).