Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst. Issue 53 (15th May 2017)
- Record Type:
- Journal Article
- Title:
- Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst. Issue 53 (15th May 2017)
- Main Title:
- Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst
- Authors:
- Ben-Daat, Hagit
Rock, Christopher L.
Flores, Marco
Groy, Thomas L.
Bowman, Amanda C.
Trovitch, Ryan J. - Abstract:
- Abstract : The κ 4 -diimine cobalt hydride compound, ( Ph2PPr DI)CoH, has been found to catalyze E -selective alkyne hydroboration and the dihydroboration of nitriles. Abstract : Addition of NaEt3 BH to ( Ph2PPr DI)CoCl2 affords the corresponding monohydride, ( Ph2PPr DI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(ii ) centre. Notably, ( Ph2PPr DI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions.
- Is Part Of:
- Chemical communications. Volume 53:Issue 53(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 53(2017)
- Issue Display:
- Volume 53, Issue 53 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 53
- Issue Sort Value:
- 2017-0053-0053-0000
- Page Start:
- 7333
- Page End:
- 7336
- Publication Date:
- 2017-05-15
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc02281f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 776.xml